Reactivity of a Piano-Stool Iron Complex toward Boranes
| dc.contributor.author | Liang, Qiuming | |
| dc.contributor.author | Garcia Mayerstein, Hector A. | |
| dc.contributor.author | Song, Datong | |
| dc.date.accessioned | 2025-04-15T13:15:56Z | |
| dc.date.available | 2025-04-15T13:15:56Z | |
| dc.date.issued | 2023-04-21 | |
| dc.description.abstract | The binding and activation of boranes by transition-metal compounds are relevant to catalytic hydroboration reactions. Herein, we report the stoichiometric reactivity of a piano-stool iron complex toward a series of boranes, where the joint action of the metal center and the ligand active site has been observed, as well as the catalytic activity of this iron complex toward the hydroboration of various N-heterocycles. | |
| dc.description.sponsorship | We thank the Natural Sciences and Engineering Research Council (NSERC) of Canada and Kamal Pharmachem Inc. for funding. We also acknowledge the Canadian Foundation for Innovation Project #19119. H.A.G.M. thanks the Mexican National Council for Science and Technology (CONACyT) for a graduate fellowship. | |
| dc.identifier.citation | Liang, Q.; Garcia Mayerstein, H. A.; Song, D. Reactivity of a Piano-Stool Iron Complex toward Boranes. Organometallics 2023, 42 (9), 816–824. DOI: 10.1021/acs.organomet.3c00037. | |
| dc.identifier.doi | 10.1021/acs.organomet.3c00037 | |
| dc.identifier.issn | 0276-7333 | |
| dc.identifier.issn | 1520-6041 | |
| dc.identifier.uri | https://hdl.handle.net/1807/142601 | |
| dc.language.iso | en | |
| dc.publication.journal | Organometallics | |
| dc.publisher | American Chemical Society (ACS) | |
| dc.relation.ispartof | Organometallics | |
| dc.subject | Aromatic Compounds | |
| dc.subject | Ligands | |
| dc.subject | Mixtures | |
| dc.subject | Pyridines | |
| dc.subject | Solutions | |
| dc.title | Reactivity of a Piano-Stool Iron Complex toward Boranes | |
| dc.type | Article Post-Print | |
| oaire.citation.issue | 9 | |
| oaire.citation.volume | 42 |